NSI for amenity=post_office - operator=Deutsche Post vs brand=Deutsche Post

I would cautiously suggest simply using an online image search. There are very different combinations, depending on the type of shop.

Some random examples:

In most cases I could not determine whether the Deutsche Post here is operator or not. And as you can see, you would have to play a lot with the branding values. Deutsche Post;DHL;Postbank or Deutsche Post;DHL or Postbank … depends on the store and services.